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Bromine → HCID 15917766, compound

HRID 1758966
Notes
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Reaction equation

HRID 1758966 reaction equation
[Cl:1][C:2]1[CH:7]=[C:6]([Cl:8])[CH:5]=[CH:4][C:3]=1[C:9]1([CH3:17])[O:13][CH:12]([CH2:14][O:15][CH3:16])[CH2:11][O:10]1.[Br:18]Br>BrBr.ClC(Cl)(Cl)Cl>[Cl:1][C:2]1[CH:7]=[C:6]([Cl:8])[CH:5]=[CH:4][C:3]=1[C:9]1([CH2:17][Br:18])[O:13][CH:12]([CH2:14][O:15][CH3:16])[CH2:11][O:10]1
ParticipantsConditionsProcedureWorkupSources & evidenceReaction notes

Participants

5

Reactant 2

HCID 24408BromineHCID 15917765HCID 15917765, compound

Product 1

HCID 15917766HCID 15917766, compound

Reagents, catalysts & solvents 2

HCID 24408BromineCatalystHCID 5943Carbon TetrachlorideSolvent

Conditions

Temperature
20 °C

Procedure

To 100 parts of 2-(2,4-dichlorophenyl)-2-methyl-4-(methoxymethyl)-1,3-dioxolane in 480 parts of tetrachloromethane are added at 45° C. a few drops of bromine till the reaction starts. Subsequently 19.6 parts of bromine are added dropwise and the whole is stirred for 2 hours at 20° C. The pale yellow solution is washed with a sodium hydrogen carbonate solution, dried and evaporated. A high vacuum distillation yields 65 parts of pure 2-(2,4-dichlorophenyl)-2-(bromomethyl)-4-(methoxymethyl)-1,3-dioxolane; bp. 129°-132° C. at 0.01 mm. pressure.

Workup

  1. washThe pale yellow solution is washed with a sodium hydrogen carbonate solution
  2. customdried
  3. customevaporated
  4. distillationA high vacuum distillation

Sources & evidence

ORD record
ord-f774e6bdfa684ab88d3186bd1a8865a4
Source dataset
uspto-grants-1982_07
DOI
10.6084/m9.figshare.5104873.v1
Patent number
US04338327

Reaction notes

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On this pageParticipantsConditionsProcedureWorkupSources & evidenceReaction notes