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Chloroform → HCID 86641263, compound

HRID 1779128
Notes
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Reaction equation

HRID 1779128 reaction equation
[CH2:1]([N:9]1[C:13](=[O:14])[CH:12]=[CH:11][C:10]1=[O:15])[CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH3:8].[C:16]1(=[O:22])[O:21][C:19](=[O:20])[CH:18]=[CH:17]1.COC(=O)C(N=NC(C)(C)C(OC)=O)(C)C.C(Cl)(Cl)Cl>CO>[CH2:1]([N:9]1[C:10](=[O:15])[CH:11]=[CH:12][C:13]1=[O:14])[CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH3:8].[C:19]1(=[O:20])[O:21][C:16](=[O:22])[CH:17]=[CH:18]1
ParticipantsProcedureWorkupSources & evidenceReaction notes

Participants

6

Reactant 4

HCID 6212ChloroformHCID 7923Maleic AnhydrideHCID 757631,1'-Dimethyl 2,2'-(1,2-diazenediyl)bis(2-methylpropanoate)HCID 512829Octyl Maleimide

Product 1

HCID 86641263HCID 86641263, compound

Reagents, catalysts & solvents 1

HCID 887Methanol
Solvent

Procedure

Into a sealed glass tube were introduced 26 g of N-n-octylmaleimide, 4.8 g of maleic anhydride, and 0.04 g of dimethyl-2,2′-azobisisobutyrate as a polymerization initiator. After nitrogen displacement, a radical polymerization reaction was conducted under the conditions of a polymerization temperature of 60° C. and a polymerization time of 5 hours. Chloroform was added after the reaction to obtain a polymer solution. Thereafter, this solution was mixed with excess methanol to thereby precipitate the polymer. The polymer obtained was taken out by filtration, subsequently sufficiently washed with methanol, and dried at 80° C. Thus, an N-n-octylmaleimide-maleic anhydride copolymer resin was obtained in an amount of 18 g. The N-n-octylmaleimide-maleic anhydride copolymer resin obtained contained maleic anhydride residue unit in an amount of 40% by weight and had a number-average molecular weight of 140,000.

Workup

  1. customAfter nitrogen displacement, a radical polymerization reaction
  2. customwas conducted under the conditions of a polymerization temperature of 60° C.
  3. customa polymerization time of 5 hours
  4. customafter the reaction
  5. customto obtain a polymer solution
  6. customto thereby precipitate the polymer
  7. customThe polymer obtained
  8. filtrationwas taken out by filtration
  9. washsubsequently sufficiently washed with methanol
  10. customdried at 80° C

Sources & evidence

ORD record
ord-b0adf2e6d29e43ffa476c87bdeb339c5
Source dataset
uspto-grants-2016_02
DOI
10.6084/m9.figshare.5104873.v1
Patent number
US09268076B2

Reaction notes

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On this pageParticipantsProcedureWorkupSources & evidenceReaction notes