4-tert-Butylcyclohexanol → 4-Tert-butylcyclohex-1-ene

HRID 1828330

Reaction equation

HRID 1828330 reaction equation
[C:1]([CH:5]1[CH2:10][CH2:9][CH:8](O)[CH2:7][CH2:6]1)([CH3:4])([CH3:3])[CH3:2].OS([O-])(=O)=O.[K+].C(OC(=O)C)C.OS([O-])(=O)=O.[K+]>>[C:1]([CH:5]1[CH2:10][CH2:9][CH:8]=[CH:7][CH2:6]1)([CH3:4])([CH3:3])[CH3:2]

Participants

4

Reactant 3

HCID 73914-tert-ButylcyclohexanolHCID 516920Potassium bisulfateHCID 86585043ethylacetate KHSO4

Product 1

HCID 166884-Tert-butylcyclohex-1-ene

Conditions

Temperature
95 °C

Procedure

20 g 4-t-butyl-1-cyclohexanol are mixed with 17 g KHSO4 and stirred for one week at 95° C. After the addition of ethylacetate KHSO4 is filtered off. Ethylacetate is evaporated and the product obtained by fractional distillation.

Workup

  1. filtrationis filtered off
  2. customEthylacetate is evaporated
  3. customthe product obtained by fractional distillation

Sources & evidence

ORD record
ord-af0b71c7642b4961a781a860d53df6c6
Source dataset
uspto-grants-2006_06
Patent number
US07057059B2

Linked notes

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