Water → Cerium triacetate
Reaction equation
O.[C:2](=[O:5])([O-])[O-:3].[Ce+3:6].[C:7](=[O:10])([O-])[O-:8].[C:11](=[O:14])([O-])[O-:12].[Ce+3]>C(O)(=O)C>[C:2]([O-:3])(=[O:5])[CH3:7].[Ce+3:6].[C:7]([O-:8])(=[O:10])[CH3:11].[C:11]([O-:12])(=[O:14])[CH3:2]Participants
4
Reactant 2
Product 1
Reagents, catalysts & solvents 1
Procedure
1147 g of water and 136 g of acetic acid were mixed and 236 g of cerium carbonate was added to form a clear solution of cerium acetate. The mixture was stirred for 48 hours to completely dissolve the carbonate. To the cerium acetate was added 512 g of zirconium acetate (20 wt % ZrO2) and stirred to make a homogeneous solution. The solution was spray dried at 110° C. to form a white powder of mixed acetates. The powder was calcined in a muffle furnace to a temperature of 500° C. for 1 hour to form the finished mixed oxide.
Sources & evidence
- ORD record
- ord-16f4708d8ca94ddcb174e92b3a64c3c5
- Source dataset
- uspto-grants-2003_03
- Patent number
- US06528451B2
Reaction notes
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