HuagongsheHuagongshe Chemistry Print Report · For research reference only
HRID 1864608Generated: October 26, 2026
2-Naphthylamine → 1-Chloro-naphthalen-2-ylamine
https://huagongshe.com/reaction/1864608
Participants
| Role | Name | HCID | Charge |
|---|
| Reactant | 2-Naphthylamine | HCID 7057 | — |
| Reactant | Chlorosuccinimide | HCID 31398 | — |
| Solvent | Carbon Tetrachloride | HCID 5943 | — |
| Product | 1-Chloro-naphthalen-2-ylamine | HCID 418014 | 96.2% |
Reaction Steps
To a CCl4 (600 mL) solution of 2-naphthylamine (10 g) at 49° C. was added NCS (9.51 g, 1.02 eq) in portions. The mixture was stirred at 49° C. for 1.5 h then concentrated to dryness to give 1-chloro-2-naphthylamine (11.94 g, 96%) as a dark solid. MS Found: (M+H)+=178.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
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| Patent number | US07625921B2 |
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| Source dataset | uspto-grants-2009_12 |
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| ORD ID | ord-b3aa8510d4024a85bb81e219ef6b4778 |
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| Source note | uspto-grants-2009_12 |
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