HCID 20975526, compound → HCID 68771976, compound

Reaction equation

[OH:1][C@H:2]1[CH2:6][CH2:5][C@H:4](/[CH:7]=[CH:8]/[CH2:9][C:10]([CH3:23])([O:16][CH:17]2[CH2:22][CH2:21][CH2:20][CH2:19][O:18]2)[CH2:11][CH2:12][CH2:13][CH2:14][CH3:15])[C@H:3]1[CH2:24][CH2:25][S:26][C:27]1[S:28][CH:29]=[C:30]([C:32]([OH:34])=[O:33])[N:31]=1.[I-].[CH4:36]>>[OH:1][C@H:2]1[CH2:6][CH2:5][C@H:4](/[CH:7]=[CH:8]/[CH2:9][C:10]([CH3:23])([O:16][CH:17]2[CH2:22][CH2:21][CH2:20][CH2:19][O:18]2)[CH2:11][CH2:12][CH2:13][CH2:14][CH3:15])[C@H:3]1[CH2:24][CH2:25][S:26][C:27]1[S:28][CH:29]=[C:30]([C:32]([O:34][CH3:36])=[O:33])[N:31]=1

Participants

Reactant 2

HCID 20975526HCID 20975526, compound

HCID 66858527HCID 66858527, compound

Product 1

HCID 68771976HCID 68771976, compound

Procedure

By the same procedure as the reaction of Example 51 using the compound 55 instead of the compound 50 and using methane iodide instead of ethane iodide, the title compound having the following physical data was obtained.

Sources & evidence

ORD record: ord-81e7023aafd848d5925ebce53122bd37
Source dataset: uspto-grants-2013_08
DOI: 10.6084/m9.figshare.5104873.v1
Patent number: US08501793B2

Reaction notes

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