2-Propanol, 1,3-dichloro-, 2-carbamate → 1,3-dichloropropan-2-yl carbamate;ditridecyl (Z)-but-2-enedioate

HRID 1902737

Reaction equation

HRID 1902737 reaction equation
[CH2:1]([Cl:9])[CH:2]([O:5][C:6]([NH2:8])=[O:7])[CH2:3][Cl:4].[C:10]([O:30][CH2:31][CH2:32][CH2:33][CH2:34][CH2:35][CH2:36][CH2:37][CH2:38][CH2:39][CH2:40][CH2:41][CH2:42][CH3:43])(=[O:29])/[CH:11]=[CH:12]\[C:13]([O:15][CH2:16][CH2:17][CH2:18][CH2:19][CH2:20][CH2:21][CH2:22][CH2:23][CH2:24][CH2:25][CH2:26][CH2:27][CH3:28])=[O:14].C(OOC1(OOC(C)(C)C)CCCCC1)(C)(C)C>>[CH2:1]([Cl:9])[CH:2]([O:5][C:6]([NH2:8])=[O:7])[CH2:3][Cl:4].[C:13]([O:15][CH2:16][CH2:17][CH2:18][CH2:19][CH2:20][CH2:21][CH2:22][CH2:23][CH2:24][CH2:25][CH2:26][CH2:27][CH3:28])(=[O:14])/[CH:12]=[CH:11]\[C:10]([O:30][CH2:31][CH2:32][CH2:33][CH2:34][CH2:35][CH2:36][CH2:37][CH2:38][CH2:39][CH2:40][CH2:41][CH2:42][CH3:43])=[O:29]

Participants

4

Reactant 3

HCID 685162-Propanol, 1,3-dichloro-, 2-carbamateHCID 763591,1-Bis(tert-butylperoxy)cyclohexaneHCID 64374272-Butenedioic acid (2Z)-, 1,4-ditridecyl ester

Product 1

HCID 1317129001,3-dichloropropan-2-yl carbamate;ditridecyl (Z)-but-2-enedioate

Conditions

Temperature
110 °C

Procedure

To a 500 ml resin kettle equipped with an overhead stirrer and containing 200 g of Flo Mo 36 C (ethoxylated castor oil) were added 50 g ditridecyl maleate and 6 g 1,1-bis(t-butylperoxy)cyclohexane (available from Witco Chemical Company under the tradename USP-400P). The mixture was then heated to 110° C. for 4 hours under nitrogen to yield a viscous liquid surfactant of the invention (Surfactant No. 54).

Workup

  1. customto yield a viscous liquid surfactant of the invention (Surfactant No. 54)

Sources & evidence

ORD record
ord-93ac40ac452242c98a3d641318cadaf8
Source dataset
uspto-grants-1982_12
Patent number
US04365024

Linked notes

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