2-Chlorobenzyl mercaptan → Emd 39593

HRID 1906740

Reaction equation

HRID 1906740 reaction equation
[Cl:1][C:2]1[CH:9]=[CH:8][CH:7]=[CH:6][C:3]=1[CH2:4][SH:5].Cl[C:11]1[C:16]2[N:17]=[CH:18][N:19]([CH3:20])[C:15]=2[CH:14]=[CH:13][N:12]=1>C(O)C>[Cl:1][C:2]1[CH:9]=[CH:8][CH:7]=[CH:6][C:3]=1[CH2:4][S:5][C:11]1[C:16]2[N:17]=[CH:18][N:19]([CH3:20])[C:15]=2[CH:14]=[CH:13][N:12]=1

Participants

4

Reactant 2

HCID 5807592-Chlorobenzyl mercaptanHCID 9487924-chloro-1-methyl-1H-imidazo(4,5-c)pyridine

Product 1

HCID 135146Emd 39593

Reagents, catalysts & solvents 1

HCID 702EthanolSolvent

Procedure

2.76 g of Na is dissolved in 180 ml of ethanol; 19.1 g of o-chlorobenzylmercaptan and 16.76 g of 4-chloro-1-methyl-1H-imidazo(4,5-c)pyridine are added; the mixture is boiled for 16 hours and evaporated; and the residue is worked up in the customary manner to give 4-o-chloro-benzylthio-1-methyl-1H-imidazo(4,5-c)pyridine of m.p. 152°-155° (from ethanol).

Workup

  1. customevaporated

Sources & evidence

ORD record
ord-356079d3f1214307a783e51e9d01b193
Source dataset
uspto-grants-1987_03
Patent number
US04654350

Linked notes

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