3-Phenyl-3,4-dihydro-1(2h)-naphthalenone → 1-Benzyl-5-(3-phenyl-3,4-dihydro-2H-naphthalen-1-ylidenemethyl)-1H-imidazole

HRID 1935758Notes

Reaction equation

HRID 1935758 reaction equation
[CH2:1]([N:8]1[C:12]([CH:13]=C2C3C(=CC=CC=3)CC2C2C=CC=CC=2)=[CH:11][N:10]=[CH:9]1)[C:2]1[CH:7]=[CH:6][CH:5]=[CH:4][CH:3]=1.[C:29]1([CH:35]2[CH2:44][C:43]3[C:38](=[CH:39][CH:40]=[CH:41][CH:42]=3)[C:37](=O)[CH2:36]2)[CH:34]=[CH:33][CH:32]=[CH:31][CH:30]=1>>[CH2:1]([N:8]1[C:12]([CH:13]=[C:37]2[C:38]3[C:43](=[CH:42][CH:41]=[CH:40][CH:39]=3)[CH2:44][CH:35]([C:29]3[CH:34]=[CH:33][CH:32]=[CH:31][CH:30]=3)[CH2:36]2)=[CH:11][N:10]=[CH:9]1)[C:2]1[CH:3]=[CH:4][CH:5]=[CH:6][CH:7]=1

Participants

3

Reactant 2

HCID 5765563-Phenyl-3,4-dihydro-1(2h)-naphthalenoneHCID 698316891-Benzyl-5-(2-phenylindan-1-ylidenemethyl)-1H-imidazole

Product 1

HCID 698323401-Benzyl-5-(3-phenyl-3,4-dihydro-2H-naphthalen-1-ylidenemethyl)-1H-imidazole

Procedure

1-Benzyl-5-(3-phenyl-3,4-dihydro-2H-naphthalen-1-ylidenemethyl)-1H-imidazole was prepared as 1-benzyl-5-(2-phenylindan-1-ylidenemethyl)-1H-imidazole above except that 3-phenyl-3,4-dihydro-2H-naphthalen-1-one (prepared according to J. Vebrel and R. Carrie Bull. Soc. Chem. Fr. (1982) 116) was used as a starting material. The crude product as its hydrochloride salt was used in the next step without purification.

Workup

  1. customThe crude product as its hydrochloride salt was used in the next step without purification

Sources & evidence

ORD record
ord-0e94f973d3c04c48978de6e9913b0df9
Source dataset
uspto-grants-2002_05
Patent number
US06388090B2

Reaction notes

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