Benzenamine, N,N-dimethyl-, hydrochloride (1:1) → N,N-dimethylanilinium tetrakis(pentafluorophenyl)borate

HRID 1938757Notes

Reaction equation

HRID 1938757 reaction equation
[F:1][C:2]1[C:7]([B-:8]([C:31]2[C:36]([F:37])=[C:35]([F:38])[C:34]([F:39])=[C:33]([F:40])[C:32]=2[F:41])([C:20]2[C:25]([F:26])=[C:24]([F:27])[C:23]([F:28])=[C:22]([F:29])[C:21]=2[F:30])[C:9]2[C:14]([F:15])=[C:13]([F:16])[C:12]([F:17])=[C:11]([F:18])[C:10]=2[F:19])=[C:6]([F:42])[C:5]([F:43])=[C:4]([F:44])[C:3]=1[F:45].[Li+].Cl.[CH3:48][N:49]([CH3:56])[C:50]1[CH:55]=[CH:54][CH:53]=[CH:52][CH:51]=1>O>[F:37][C:36]1[C:31]([B-:8]([C:9]2[C:14]([F:15])=[C:13]([F:16])[C:12]([F:17])=[C:11]([F:18])[C:10]=2[F:19])([C:7]2[C:6]([F:42])=[C:5]([F:43])[C:4]([F:44])=[C:3]([F:45])[C:2]=2[F:1])[C:20]2[C:21]([F:30])=[C:22]([F:29])[C:23]([F:28])=[C:24]([F:27])[C:25]=2[F:26])=[C:32]([F:41])[C:33]([F:40])=[C:34]([F:39])[C:35]=1[F:38].[CH3:48][NH+:49]([CH3:56])[C:50]1[CH:55]=[CH:54][CH:53]=[CH:52][CH:51]=1

Participants

4

Reactant 2

HCID 79987Benzenamine, N,N-dimethyl-, hydrochloride (1:1)HCID 23709652Lithium tetrakis(pentafluorophenyl)borate

Product 1

HCID 10996402N,N-dimethylanilinium tetrakis(pentafluorophenyl)borateYield 71.3%

Reagents, catalysts & solvents 1

HCID 962WaterSolvent

Procedure

Thereafter, lithium tetrakis(pentafluorophenyl)borate (16 mmol) was reacted with dimethylaniline hydrochloride (16 mmol) in water, to obtain 11.4 mmol of dimethylanilinium tetrakis(pentafluorophenyl)borate as a white solid product.

Sources & evidence

ORD record
ord-5247338b4e7944848a58c433247a1640
Source dataset
uspto-grants-1997_12
Patent number
US05693728

Reaction notes

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