Methyl (4-acetylphenyl)acetate → Methyl [4-(bromoacetyl)phenyl]acetate

Reaction equation

[C:1]([C:4]1[CH:9]=[CH:8][C:7]([CH2:10][C:11]([O:13][CH3:14])=[O:12])=[CH:6][CH:5]=1)(=[O:3])[CH3:2].[Br:15]C1COCCO1>>[Br:15][CH2:2][C:1]([C:4]1[CH:9]=[CH:8][C:7]([CH2:10][C:11]([O:13][CH3:14])=[O:12])=[CH:6][CH:5]=1)=[O:3]

Participants

Reactant 2

HCID 15568000Methyl (4-acetylphenyl)acetate

HCID 219826212-Bromo-1,4-dioxane

Product 1

HCID 15568002Methyl [4-(bromoacetyl)phenyl]acetate

Procedure

Prepared from methyl 4-acetyl-phenylacetate and bromodioxan.

Sources & evidence

ORD record: ord-b972a27773b24f9ea9c3667d5b124102
Source dataset: uspto-grants-1997_12
DOI: 10.6084/m9.figshare.5104873.v1
Patent number: US05700801

Reaction notes

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