(2R,3R,4S,5S)-2,3,4,5-tetrahydroxyhexanal → HCID 25032981, compound

HRID 1941737Notes

Reaction equation

HRID 1941737 reaction equation
[O:1]=[CH:2][C@@H:3]([C@@H:5]([C@H:7]([C@H:9]([CH3:11])[OH:10])[OH:8])[OH:6])[OH:4].OCC([C@H]([C@@H]([C@H](C)O)O)O)=O.OCC([C@H]([C@H]([C@@H](CO)O)O)O)=O>>[OH:1][CH2:2][C:3]([C@H:5]([C@H:7]([C@H:9]([CH3:11])[OH:10])[OH:8])[OH:6])=[O:4]

Participants

4

Reactant 3

HCID 19233(2R,3R,4S,5S)-2,3,4,5-tetrahydroxyhexanal2×HCID 92092(3S,4S,5R)-1,3,4,5,6-pentahydroxyhexan-2-oneHCID 4393306-deoxy-L-sorbose

Product 1

HCID 25032981HCID 25032981, compound

Procedure

Using L-rhamnose isomerase, L-rhamnose is isomerized to L-rhamnulose (6-deoxy L-fructose), which is then epimerized with D-tagatose 3-epimerase to produce 6-deoxy L-psicose.

Sources & evidence

ORD record
ord-cf190eec182043baa75add336841ab2a
Source dataset
uspto-grants-2013_03
Patent number
US08389248B2

Reaction notes

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