Potassium bisulfide → Potassium phenylthiomethyldithiocarbamate

HRID 1973579Notes

Reaction equation

HRID 1973579 reaction equation
[C:1]1([S:7][CH2:8][N:9]=[C:10]=[S:11])[CH:6]=[CH:5][CH:4]=[CH:3][CH:2]=1.[SH-:12].[K+:13]>CC(C)=O.C(O)(C)(C)C>[C:1]1([S:7][CH2:8][NH:9][C:10](=[S:12])[S-:11])[CH:6]=[CH:5][CH:4]=[CH:3][CH:2]=1.[K+:13]

Participants

4

Reactant 2

HCID 102109Potassium bisulfideHCID 13240489Phenylthiomethyl isothiocyanate

Product 1

HCID 23667329Potassium phenylthiomethyldithiocarbamate

Reagents, catalysts & solvents 1

HCID 19966414t-BuOH acetoneSolvent

Procedure

Potassium phenylthiomethyldithiocarbamate was prepared by the reaction of phenylthiomethyl isothiocyanate and potassium hydrosulfide in a t-butyl alcohol acetone mixture.

Sources & evidence

ORD record
ord-f13796315f32451ea990f91f6a85f531
Source dataset
uspto-grants-1976_12
Patent number
US03997668

Reaction notes

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