Picryl Chloride → 2',4',6'-Trinitro-4-methylbiphenyl

HRID 1976500

Reaction equation

HRID 1976500 reaction equation
I[C:2]1[CH:7]=[CH:6][C:5]([CH3:8])=[CH:4][CH:3]=1.[C:9]1(Cl)[C:10](=[CH:14][C:15](=[CH:19][C:20]=1[N+:21]([O-:23])=[O:22])[N+:16]([O-:18])=[O:17])[N+:11]([O-:13])=[O:12]>[Cu]>[N+:21]([C:20]1[CH:19]=[C:15]([N+:16]([O-:18])=[O:17])[CH:14]=[C:10]([N+:11]([O-:13])=[O:12])[C:9]=1[C:2]1[CH:7]=[CH:6][C:5]([CH3:8])=[CH:4][CH:3]=1)([O-:23])=[O:22]

Participants

4

Reactant 2

HCID 6953Picryl ChlorideHCID 122074-Iodotoluene

Product 1

HCID 223420002',4',6'-Trinitro-4-methylbiphenyl

Reagents, catalysts & solvents 1

HCID 23978CopperCatalyst

Procedure

4-iodotoluene is reacted with picryl chloride in the presence of copper bronze at 215° C. to yield 2′,4′,6′-trinitro-4-methylbiphenyl (1).

Sources & evidence

ORD record
ord-063e3bc33f5f4e6eb671b697d51bd567
Source dataset
uspto-grants-2001_05
Patent number
US06226352B1

Linked notes

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