Sodium Hydroxide → HCID 13997673, compound

HRID 1977266Notes

Reaction equation

HRID 1977266 reaction equation
C[O:2][C:3](=[O:16])[C:4]1[CH:9]=[CH:8][CH:7]=[C:6]([O:10][CH2:11][CH2:12][CH2:13][CH2:14][CH3:15])[CH:5]=1.[OH-].[Na+].OCl>CO>[CH2:11]([O:10][C:6]1[CH:5]=[C:4]([CH:9]=[CH:8][CH:7]=1)[C:3]([OH:16])=[O:2])[CH2:12][CH2:13][CH2:14][CH3:15]

Participants

5

Reactant 3

HCID 14798Sodium HydroxideHCID 24341Hypochlorous AcidHCID 18342002Methyl 3-(pentyloxy)benzoate

Product 1

HCID 13997673HCID 13997673, compoundYield 0.1%

Reagents, catalysts & solvents 1

HCID 887MethanolSolvent

Procedure

To 3-amyloxybenzoic acid methyl ester (35 g) in methanol (200 ml) was added 1N-sodium hydroxide aqueous solution (200 ml) and the mixture was stirred for 2 days at room temperature. Hydroxy chloride (20 ml) was added to the raction mixture. The precipitate was filtered and washed with water, acetonitrile and diisopropyl ether to give 3-amyloxybenzoic acid (30 mg).

Workup

  1. filtrationThe precipitate was filtered
  2. washwashed with water, acetonitrile and diisopropyl ether

Sources & evidence

ORD record
ord-eabdd1dd6f314dd5b90acfe550ac6820
Source dataset
uspto-grants-2001_05
Patent number
US06232290B1

Reaction notes

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