HuagongsheHuagongshe Chemistry Print Report · For research reference only
2-Methyl-3,4,5-trichloroisothiazolium fluorosulfonate → 4,5-Dichloro-2-methyl-4-isothiazolin-3-one
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | 2-Methyl-3,4,5-trichloroisothiazolium fluorosulfonate | HCID 12889022 | — |
| Solvent | Sodium Acetate | HCID 517045 | — |
| Product | 4,5-Dichloro-2-methyl-4-isothiazolin-3-one | HCID 147017 | 70.3% |
Reaction Steps
2-Methyl-3,4,5-trichloroisothiazolium fluorosulfonate (16.9 g, 0.058 mol) was added in portions to 150 ml of a saturated sodium acetate solution. After stirring for 30 min. the solid was collected, washed with water, and recrystallized from ethanol to yield 7.5 g (70%) of 4,5-dichloro-2-methyl-4-isothiazolin-3-one, mp 119°-120°.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04508908 |
| Source dataset | uspto-grants-1985_04 |
| ORD ID | ord-72c5f81b3a8747988a0b633c2c04b580 |
| Source note | uspto-grants-1985_04 |