Benzylamine → 3-Benzylaminoacrylonitrile

HRID 2058790

Reaction equation

HRID 2058790 reaction equation
[CH2:1]([NH2:8])[C:2]1[CH:7]=[CH:6][CH:5]=[CH:4][CH:3]=1>C(O)C>[CH2:1]([NH:8][CH:3]=[CH:2][C:1]#[N:8])[C:2]1[CH:7]=[CH:6][CH:5]=[CH:4][CH:3]=1

Participants

3

Reactant 1

HCID 7504Benzylamine

Product 1

HCID 705487013-BenzylaminoacrylonitrileYield 72.1%

Reagents, catalysts & solvents 1

HCID 702EthanolSolvent

Procedure

9.7 g (0.1 mol) of 3-EAN and 21.4 g (0.2 mol) of benzylamine are refluxed for 4 h with removal of ethanol by distillation. Subsequent vacuum distillation yields 11.4 g of 3-benzylaminoacrylonitrile (72% with respect to 3-EAN).

Workup

  1. distillationSubsequent vacuum distillation

Sources & evidence

ORD record
ord-c179ea1549da4dd3b03926fca0d158d9
Source dataset
uspto-grants-1982_03
Patent number
US04319024

Linked notes

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