Hydrazine → Tetradecanehydrazide

HRID 2081661Notes

Reaction equation

HRID 2081661 reaction equation
[NH2:1][NH2:2].[C:3]([O:18]C)(=O)[CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][CH2:12][CH2:13][CH2:14][CH2:15][CH3:16]>CO>[C:3]([NH:1][NH2:2])(=[O:18])[CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][CH2:12][CH2:13][CH2:14][CH2:15][CH3:16]

Participants

4

Reactant 2

HCID 9321HydrazineHCID 31284Methyl Myristate

Product 1

HCID 2748033TetradecanehydrazideYield 43.9%

Reagents, catalysts & solvents 1

HCID 887MethanolSolvent

Procedure

Hydrazine (1.9 mL, 0.058 mol) was added to a solution of methyl tetradecanoate (13.96 g, 0.058 mol) in methanol (300 mL) and the solution refluxed for 3 days. The mixture was allowed to cool and filtered to yield 6.17 g of a crystalline solid, m.p. 107°-111° C.

Workup

  1. temperaturethe solution refluxed for 3 days
  2. temperatureto cool
  3. filtrationfiltered

Sources & evidence

ORD record
ord-afcf65b2ba08436fa2698374f5ed43d2
Source dataset
uspto-grants-1993_02
Patent number
US05185358

Reaction notes

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