n,n'-Dipropylhexane-1,6-diamine → N,N'-(1,6-hexylene)-bis[N-propyl-2-hydroxyundecylamine]

Reaction equation

[CH2:1]1[O:12][CH:2]1[CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH3:11].[CH2:13]([NH:16][CH2:17][CH2:18][CH2:19][CH2:20][CH2:21][CH2:22][NH:23][CH2:24][CH2:25][CH3:26])[CH2:14][CH3:15]>>[CH2:17]([N:16]([CH2:1][CH:2]([OH:12])[CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH3:11])[CH2:13][CH2:14][CH3:15])[CH2:18][CH2:19][CH2:20][CH2:21][CH2:22][N:23]([CH2:1][CH:2]([OH:12])[CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH3:11])[CH2:24][CH2:25][CH3:26]

Participants

Reactant 2

HCID 285228n,n'-Dipropylhexane-1,6-diamine

HCID 5377372-Nonyloxirane

Product 1

HCID 21332397N,N'-(1,6-hexylene)-bis[N-propyl-2-hydroxyundecylamine]

Procedure

Condensation of 1-undecene oxide and N,N'-dipropylhexamethylenediamine affords N,N'-(1,6-hexylene)-bis[N-propyl-2-hydroxyundecylamine] (I: R = CH3 (CH2)8, R' = CH3 (CH2)2, X = (CH2)6, Z = H).

Sources & evidence

ORD record: ord-9424fef79e594e78966f182038b09fec
Source dataset: uspto-grants-1978_04
DOI: 10.6084/m9.figshare.5104873.v1
Patent number: US04085144

Reaction notes

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