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Sodium Hydroxide → Zinc Dodecyl Fumarate

HRID 2107149
Notes
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Reaction equation

HRID 2107149 reaction equation
[C:1]([O:8][CH2:9][CH2:10][CH2:11][CH2:12][CH2:13][CH2:14][CH2:15][CH2:16][CH2:17][CH2:18][CH2:19][CH3:20])(=[O:7])/[CH:2]=[CH:3]/[C:4]([O-:6])=[O:5].[OH-].[Na+].O.O.C([O-])(=O)C.[Zn+2:29].C([O-])(=O)C>CC(C)=O>[C:1]([O:8][CH2:9][CH2:10][CH2:11][CH2:12][CH2:13][CH2:14][CH2:15][CH2:16][CH2:17][CH2:18][CH2:19][CH3:20])(=[O:7])/[CH:2]=[CH:3]/[C:4]([O-:6])=[O:5].[Zn+2:29].[CH2:9]([O:8][C:1](=[O:7])/[CH:2]=[CH:3]/[C:4]([O-:6])=[O:5])[CH2:10][CH2:11][CH2:12][CH2:13][CH2:14][CH2:15][CH2:16][CH2:17][CH2:18][CH2:19][CH3:20]
ParticipantsConditionsProcedureWorkupSources & evidenceReaction notes

Participants

5

Reactant 3

HCID 14798Sodium HydroxideHCID 2724192Zinc acetate (USP)HCID 22320807HCID 22320807, compound

Product 1

HCID 86744016Zinc Dodecyl Fumarate

Reagents, catalysts & solvents 1

HCID 180AcetoneSolvent

Conditions

Temperature
50 °C

Procedure

To a 12 percent w/v acetone suspension of the monododecyl fumarate heated to 50° C. is added 1.0 molar equivalent sodium hydroxide (299 g) as a 10 percent w/v aqueous solution. After the stirred suspension clears, 0.5 molar equivalent zinc acetate dihydrate (110 g) as a saturated aqueous solution is added with stirring. The supernatant liquid is separated from the precipitated zinc dodecyl fumarate.

Workup

  1. customThe supernatant liquid is separated from the precipitated zinc dodecyl fumarate

Sources & evidence

ORD record
ord-7c6d20a288c04e8daed69e554eafc90c
Source dataset
uspto-grants-1990_06
DOI
10.6084/m9.figshare.5104873.v1
Patent number
US04933405

Reaction notes

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On this pageParticipantsConditionsProcedureWorkupSources & evidenceReaction notes