Dibenzylhydroxylamine → HCID 14224083, compound

HRID 2118562

Reaction equation

HRID 2118562 reaction equation
[CH2:1]([N:8]([CH2:10][C:11]1[CH:16]=[CH:15][CH:14]=[CH:13][CH:12]=1)[OH:9])[C:2]1[CH:7]=[CH:6][CH:5]=[CH:4][CH:3]=1.[CH2:17]([N:35]1[C:39](=[O:40])[CH:38]=[CH:37][C:36]1=[O:41])[CH2:18][CH2:19][CH2:20][CH2:21][CH2:22][CH2:23][CH2:24][CH2:25][CH2:26][CH2:27][CH2:28][CH2:29][CH2:30][CH2:31][CH2:32][CH2:33][CH3:34]>>[CH2:17]([N:35]1[C:36](=[O:41])[CH2:37][CH:38]([O:9][N:8]([CH2:1][C:2]2[CH:3]=[CH:4][CH:5]=[CH:6][CH:7]=2)[CH2:10][C:11]2[CH:16]=[CH:15][CH:14]=[CH:13][CH:12]=2)[C:39]1=[O:40])[CH2:18][CH2:19][CH2:20][CH2:21][CH2:22][CH2:23][CH2:24][CH2:25][CH2:26][CH2:27][CH2:28][CH2:29][CH2:30][CH2:31][CH2:32][CH2:33][CH3:34]

Participants

3

Reactant 2

HCID 69297DibenzylhydroxylamineHCID 871181-octadecyl-1H-pyrrole-2,5-dione

Product 1

HCID 14224083HCID 14224083, compound

Procedure

The procedure of Example 1 is repeated using 6.10 g (29 mmole) of N,N-dibenzylhydroxylamine and 10.0 g (29 mmole) of N-n-octadecylmaleimide. The residue is purified by preparative HPLC (Silica gel: 9:1 heptane:ethyl acetate eluent) to give 8.0 g (49%) of a waxy solid.

Workup

  1. customThe residue is purified by preparative HPLC (Silica gel: 9:1 heptane:ethyl acetate eluent)
  2. customto give 8.0 g (49%) of a waxy solid

Sources & evidence

ORD record
ord-0b85d6a48ba1415095c7ab32c6b3787b
Source dataset
uspto-grants-1987_07
Patent number
US04678826

Linked notes

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