22-Hydroxydocosanoic acid → 22-Oxodocosanoic acid

HRID 217089

Reaction equation

HRID 217089 reaction equation
[OH:1][CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][CH2:12][CH2:13][CH2:14][CH2:15][CH2:16][CH2:17][CH2:18][CH2:19][CH2:20][CH2:21][CH2:22][C:23]([OH:25])=[O:24].[Cr](Cl)([O-])(=O)=O.[NH+]1C=CC=CC=1>>[O:1]=[CH:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][CH2:12][CH2:13][CH2:14][CH2:15][CH2:16][CH2:17][CH2:18][CH2:19][CH2:20][CH2:21][CH2:22][C:23]([OH:25])=[O:24]

Participants

3

Reactant 2

HCID 528292222-Hydroxydocosanoic acidHCID 178418287HCID 178418287, compound

Product 1

HCID 5294014522-Oxodocosanoic acid

Procedure

3.9 g 22-Hydroxy-docosanoic acid (1 eq.) was oxidized with 4.72 g PCC (Pyridinium chlorochromate) (2 eq.) for about 2 hours under reflux as described in example 1, step a.

Workup

  1. temperatureunder reflux

Sources & evidence

ORD record
ord-55d4c4d3ee87488d9289ed9ac6c978ea
Source dataset
uspto-grants-2012_06
Patent number
US08193246B2

Linked notes

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