4-Chlorotoluene → Tris(4-methylphenyl)sulfanium Chloride
Reaction equation
[CH3:1][C:2]1[CH:7]=[CH:6][C:5]([S:8]([C:10]2[CH:15]=[CH:14][C:13]([CH3:16])=[CH:12][CH:11]=2)=O)=[CH:4][CH:3]=1.[Cl:17][C:18]1[CH:23]=[CH:22][C:21]([CH3:24])=[CH:20][CH:19]=1>>[Cl-:17].[CH3:1][C:2]1[CH:7]=[CH:6][C:5]([S+:8]([C:18]2[CH:23]=[CH:22][C:21]([CH3:24])=[CH:20][CH:19]=2)[C:10]2[CH:15]=[CH:14][C:13]([CH3:16])=[CH:12][CH:11]=2)=[CH:4][CH:3]=1Participants
3
Procedure
The intended compound was obtained by a similar manner to that in Synthesis Example 1 except that bis(4-methylphenyl)sulfoxide instead of diphenyl sulfoxide and 4-chlorotoluene instead of chlorobenzene were used, and the amount of water in the extraction was increased.
Workup
- customThe intended compound was obtained by a similar manner to that
- extractionthe amount of water in the extraction
- temperaturewas increased
Sources & evidence
- ORD record
- ord-6fd997a3705a4e11a6dd4f0f84b6db60