1-Bromo-4-tert-butylbenzene → Tris(4-tert-butylphenyl)sulfanium bromide
Reaction equation
[C:1]([C:5]1[CH:10]=[CH:9][C:8]([S:11]([C:13]2[CH:18]=[CH:17][C:16]([C:19]([CH3:22])([CH3:21])[CH3:20])=[CH:15][CH:14]=2)=O)=[CH:7][CH:6]=1)([CH3:4])([CH3:3])[CH3:2].[C:23]([C:27]1[CH:32]=[CH:31][C:30]([Br:33])=[CH:29][CH:28]=1)([CH3:26])([CH3:25])[CH3:24]>>[Br-:33].[C:1]([C:5]1[CH:10]=[CH:9][C:8]([S+:11]([C:30]2[CH:31]=[CH:32][C:27]([C:23]([CH3:26])([CH3:25])[CH3:24])=[CH:28][CH:29]=2)[C:13]2[CH:18]=[CH:17][C:16]([C:19]([CH3:22])([CH3:21])[CH3:20])=[CH:15][CH:14]=2)=[CH:7][CH:6]=1)([CH3:4])([CH3:3])[CH3:2]Participants
3
Procedure
The intended compound was obtained by a similar manner to that in Synthesis Example 1 except that bis(4-tert-butylphenyl)sulfoxide instead of diphenyl sulfoxide and 4-tert-butylbromobenzene instead of chlorobenzene were used, and the amount of water in the extraction was increased.
Workup
- customThe intended compound was obtained by a similar manner to that
- extractionthe amount of water in the extraction
- temperaturewas increased