Stannous Chloride → 5-Methyl-2-p-tolylsulfanyl-phenylamine
Reaction equation
[CH3:1][C:2]1[CH:7]=[CH:6][C:5]([S:8][C:9]2[CH:14]=[CH:13][C:12]([CH3:15])=[CH:11][CH:10]=2)=[C:4]([N+:16]([O-])=O)[CH:3]=1.Cl[Sn]Cl>>[CH3:1][C:2]1[CH:7]=[CH:6][C:5]([S:8][C:9]2[CH:14]=[CH:13][C:12]([CH3:15])=[CH:11][CH:10]=2)=[C:4]([NH2:16])[CH:3]=1Participants
3
Procedure
The product from Example 47a was reduced with SnCl2 following the procedure from Example 1f giving the title compound.
Sources & evidence
- ORD record
- ord-fe552d0a5c4b46bb88c191844e43cdec
- Source dataset
- uspto-grants-2012_12
- Patent number
- US08338605B2
Reaction notes
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