Allyl bromide → Methyl 4-{3-[(prop-2-en-1-yl)oxy]phenoxy}benzoate

Reaction equation

[OH:1][C:2]1[CH:3]=[C:4]([CH:16]=[CH:17][CH:18]=1)[O:5][C:6]1[CH:15]=[CH:14][C:9]([C:10]([O:12][CH3:13])=[O:11])=[CH:8][CH:7]=1.[CH2:19](Br)[CH:20]=[CH2:21]>>[CH2:21]([O:1][C:2]1[CH:3]=[C:4]([CH:16]=[CH:17][CH:18]=1)[O:5][C:6]1[CH:15]=[CH:14][C:9]([C:10]([O:12][CH3:13])=[O:11])=[CH:8][CH:7]=1)[CH:20]=[CH2:19]

Participants

Reactant 2

HCID 7841Allyl bromide

HCID 19375802HCID 19375802, compound

Product 1

HCID 19375796Methyl 4-{3-[(prop-2-en-1-yl)oxy]phenoxy}benzoateYield 96%

Procedure

The title compound was prepared in 96% yield as an oil from methyl 4-(3-hydroxyphenoxy)benzoate and allyl bromide by the procedure of Preparation 36. NMR.

Sources & evidence

ORD record: ord-c9f3fe53b264401f973d8f69b6f0c652
Source dataset: uspto-grants-1995_10
DOI: 10.6084/m9.figshare.5104873.v1
Patent number: US05462954

Reaction notes

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