Heptanal → N-heptylidene-(2-methylpropenylamine)

Reaction equation

[CH:1](=O)[CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH3:7].[CH2:9]([NH2:13])[C:10](=[CH2:12])[CH3:11]>>[CH:1](=[N:13][CH:9]=[C:10]([CH3:12])[CH3:11])[CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH3:7]

Participants

Reactant 2

HCID 8130Heptanal

HCID 761412-Methylallylamine

Product 1

HCID 20436098N-heptylidene-(2-methylpropenylamine)

Procedure

The N-heptylidene-(2-methylpropenylamine) was prepared from heptanal and methallylamine, with subsequent isomerisation of the reaction product with potassium tert.-butylate; boiling point 54° C./5 Pa; nD20 =1.4662.

Sources & evidence

ORD record: ord-adca4dabb0d24d2a9e2f9e5c52f2885c
Source dataset: uspto-grants-1982_10
DOI: 10.6084/m9.figshare.5104873.v1
Patent number: US04355177

Reaction notes

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