HCID 15828909, compound → HCID 131720112, compound

HRID 2257239

Reaction equation

HRID 2257239 reaction equation
[C:1]1([CH2:7][C:8]([OH:19])([C:14]([O:16]CC)=[O:15])[C:9]([O:11]CC)=[O:10])[CH:6]=[CH:5][CH:4]=[CH:3][CH:2]=1.CO.[Li+:22].[OH-]>CO>[Li+:22].[C:1]1([CH2:7][C:8]([OH:19])([C:14]([OH:16])=[O:15])[C:9]([O-:11])=[O:10])[CH:2]=[CH:3][CH:4]=[CH:5][CH:6]=1

Participants

4

Reactant 2

HCID 15828909HCID 15828909, compoundHCID 23717829Lithium hydroxide methanol

Product 1

HCID 131720112HCID 131720112, compound

Reagents, catalysts & solvents 1

HCID 887MethanolSolvent

Procedure

2 g of the ester are treated in MeOH with aqueous-methanol LiOH, as described above, to give 1.2 g of 3-phenyl-2-hydroxy-2-carboxy propanoic acid lithium salt, m.p. >300° C.:, I.R. 3400, 1640 cm-1 ; HNMR (D20) δ (TMS): 3,4 s, 7.2-7.35 m.

Sources & evidence

ORD record
ord-d0ad9e3d69754a09ab60cd9e6cdfd5bb
Source dataset
uspto-grants-1997_08
Patent number
US05656656

Linked notes

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