Prop-2-en-1-yl 3-nitrobenzoate → Allyl 3-aminobenzoate
Reaction equation
[N+:1]([C:4]1[CH:5]=[C:6]([CH:13]=[CH:14][CH:15]=1)[C:7]([O:9][CH2:10][CH:11]=[CH2:12])=[O:8])([O-])=O>CO>[NH2:1][C:4]1[CH:5]=[C:6]([CH:13]=[CH:14][CH:15]=1)[C:7]([O:9][CH2:10][CH:11]=[CH2:12])=[O:8]Participants
3
Reagents, catalysts & solvents 1
Procedure
Reduction of the above nitro compound by the method of Example 2, except that the solvent was methanol, gave allyl 3-aminobenzoate. Nmr (CDCl3): δ3.38 (br, 2H); 4.79 (dt, 2H); 5.24-5.44 (m, 2H); 5.93-6.09 (m, 1H); 6.86 (dm, 1H); 7.21 (t, 1H); 7.37 (t, 1H); 7.45 (dt, 1H).
Sources & evidence
- ORD record
- ord-5661aa7e63b747d7bb19892e37712fc5
- Source dataset
- uspto-grants-1995_12
- Patent number
- US05478820
Reaction notes
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