Cyclopentadiene → 4,7-Methano-1H-indene, octahydro-

HRID 2287259

Reaction equation

HRID 2287259 reaction equation
[CH:1]1[CH2:5][CH:4]=[CH:3][CH:2]=1>[Ni]>[CH2:2]1[CH2:1][CH:5]2[CH:4]([CH:2]3[CH2:1][CH:5]2[CH2:4][CH2:3]3)[CH2:3]1

Participants

3

Reactant 1

HCID 7612Cyclopentadiene

Product 1

HCID 177954,7-Methano-1H-indene, octahydro-

Reagents, catalysts & solvents 1

HCID 935NickelCatalyst

Procedure

hydrogenating the endo dimer of cyclopentadiene containing a dispersed nickel hydrogenation catalyst to provide a crude endo-tetrahydrodicyclopentadiene derivative having a melting point of at least about 70° C,;

Sources & evidence

ORD record
ord-b3018da4b78c47e78e686c7bd1834494
Source dataset
uspto-grants-1981_05
Patent number
US04270014

Linked notes

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