Aluminium lithium hydride → 2-Heptylpropane-1,3-diol

HRID 2292399

Reaction equation

HRID 2292399 reaction equation
C([O:3][C:4]([CH:6]([C:16](OCC)=[O:17])[CH:7]([CH2:9][CH2:10][CH2:11][CH2:12][CH2:13][CH2:14]C)C)=O)C.[H-].[Al+3].[Li+].[H-].[H-].[H-]>>[CH2:7]([CH:6]([CH2:4][OH:3])[CH2:16][OH:17])[CH2:9][CH2:10][CH2:11][CH2:12][CH2:13][CH3:14]

Participants

3

Reactant 2

HCID 21226445Aluminium lithium hydrideHCID 124121385Diethyl(2-n-heptylpropanedicarboxylate)

Product 1

HCID 2255562-Heptylpropane-1,3-diol

Procedure

Quantities: compound from Example 3 (72.2 g, 0.3 mol) and lithium aluminum hydride (20 g, 0.53 mol). The experimental procedure was as described in Example 6. The pure product was recrystallised from light petrol/ethyl acetate; (49:1).

Workup

  1. customThe pure product was recrystallised from light petrol/ethyl acetate

Sources & evidence

ORD record
ord-18e5afd068044c5893e7e57590a4ce3d
Source dataset
uspto-grants-1997_11
Patent number
US05683623

Linked notes

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