Diethyl(2-n-octylpropanedicarboxylate) → 2-Octylpropane-1,3-diol

Reaction equation

C([O:3][C:4]([CH:6]([C:17](OCC)=[O:18])[CH:7]([CH2:9][CH2:10][CH2:11][CH2:12][CH2:13][CH2:14][CH2:15]C)C)=O)C.[H-].[Al+3].[Li+].[H-].[H-].[H-]>>[CH2:7]([CH:6]([CH2:4][OH:3])[CH2:17][OH:18])[CH2:9][CH2:10][CH2:11][CH2:12][CH2:13][CH2:14][CH3:15]

Participants

Reactant 2

HCID 19591342Diethyl(2-n-octylpropanedicarboxylate)

HCID 21226445Aluminium lithium hydride

Product 1

HCID 3160622-Octylpropane-1,3-diol

Procedure

Quantities: compound from Example 4 (76.5 g, 0.28 mol) and lithium aluminum hydride (23 g, 0.6 mol). The experimental procedure was as described in Example 6. The product was obtained as a colourless solid.

Workup

customThe product was obtained as a colourless solid

Sources & evidence

ORD record: ord-8a1ad9e076014e0bb0b55b6271ae075d
Source dataset: uspto-grants-1997_11
DOI: 10.6084/m9.figshare.5104873.v1
Patent number: US05683623

Reaction notes

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