Ethanol, 2,2'-((4-fluoro-3-nitrophenyl)imino)bis- → HCID 21475498, compound

Reaction equation

[N+:1]([C:4]1C=C(N)C=[CH:8][C:9]=1NCC=C)([O-])=O.F[C:16]1[CH:21]=[CH:20][C:19]([N:22]([CH2:26][CH2:27][OH:28])[CH2:23][CH2:24][OH:25])=[CH:18][C:17]=1[N+:29]([O-:31])=[O:30]>>[N+:29]([C:17]1[CH:18]=[C:19]([N:22]([CH2:26][CH2:27][OH:28])[CH2:23][CH2:24][OH:25])[CH:20]=[CH:21][C:16]=1[NH:1][CH2:4][CH:9]=[CH2:8])([O-:31])=[O:30]

Participants

Reactant 2

HCID 122457Ethanol, 2,2'-((4-fluoro-3-nitrophenyl)imino)bis-

HCID 23500036N-(2-Nitro-4-aminophenyl)-allylamine

Product 1

HCID 21475498HCID 21475498, compound

Procedure

Synthesis and working up same as for compound 1, but with 4-fluoro-3-nitro-N,N-bis-(2-hydroxyethyl)-aminobenzene instead of 4-fluoro-3-nitroaminobenzene. Black crystals, melting point 73°-75° C.

Workup

customSynthesis

Sources & evidence

ORD record: ord-a18139bbb88e49eb818b86ab09628e13
Source dataset: uspto-grants-1997_11
DOI: 10.6084/m9.figshare.5104873.v1
Patent number: US05685881

Reaction notes

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