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Toluene → HCID 54175339, compound

HRID 2295706
Notes
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Reaction equation

HRID 2295706 reaction equation
Cl[CH2:2]C=CC=C.[CH3:7][C:8]([CH:10]([CH3:12])[CH3:11])=[O:9].[OH-].[K+].[C:15]1([CH3:21])[CH:20]=CC=[CH:17][CH:16]=1>>[CH3:11][C:10]([CH3:2])([CH2:12][CH:20]=[C:15]([CH3:21])[CH:16]=[CH2:17])[C:8](=[O:9])[CH3:7]
ParticipantsProcedureSources & evidenceReaction notes

Participants

5

Reactant 4

HCID 1140TolueneHCID 112513-Methyl-2-butanoneHCID 14797Potassium HydroxideHCID 53837795HCID 53837795, compound

Product 1

HCID 54175339HCID 54175339, compound

Procedure

According to the procedure described in Example 1, from 58.1 g of 1-chloro-2,4-pentadiene and 45.2 g of isopropyl methyl ketone in the presence of 100 g of powdered potassium hydroxide in 300 ml of toluene there are obtained 49.9 g of crude 3,3,6-trimethyl-5,7-octadien-2-one which are subjected to a fraction distillation.

Sources & evidence

ORD record
ord-2ee2a58664994cbbadd41f6a013f820c
Source dataset
uspto-grants-1984_01
DOI
10.6084/m9.figshare.5104873.v1
Patent number
US04426321

Reaction notes

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On this pageParticipantsProcedureSources & evidenceReaction notes