Ethyl sulfide → HCID 86743413, compound

Reaction equation

[CH2:1]([S:3][CH2:4][CH3:5])[CH3:2].[CH2:6]([I:28])[CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][CH2:12][CH2:13][CH2:14][CH2:15][CH2:16][CH2:17][CH2:18][CH2:19][CH2:20][CH2:21][CH2:22][CH2:23][CH2:24][CH2:25][CH2:26][CH3:27]>>[I-:28].[CH2:1]([S+:3]([CH2:4][CH3:5])[CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][CH2:12][CH2:13][CH2:14][CH2:15][CH2:16][CH2:17][CH2:18][CH2:19][CH2:20][CH2:21][CH2:22][CH2:23][CH2:24][CH2:25][CH2:26][CH3:27])[CH3:2]

Participants

Reactant 2

HCID 9609Ethyl sulfide

HCID 132572191-Iododocosane

Product 1

HCID 86743413HCID 86743413, compound

Procedure

Diethyl sulphide is quaternized by docosyl iodide in order to obtain diethyldocosylsulphonium iodide. This iodide is then placed in an alcoholic solution with an equivalent of the TCNQ lithium salt. This gives crystals, which are recrystallized in alcohol. These crystals are constituted by the simple tetracyanoquinodimethane diethyl docosyl sulphonium salt of formula: ##STR4##

Sources & evidence

ORD record: ord-c8b229f5aef446ccb6a3461411dca00c
Source dataset: uspto-grants-1989_10
DOI: 10.6084/m9.figshare.5104873.v1
Patent number: US04871680

Reaction notes

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