HuagongsheHuagongshe Chemistry Print Report · For research reference only
Water → 7,12-Dioxaspiro(5,6)dodec-9-ene
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Water | HCID 962 | — |
| Reactant | Cyclohexanone | HCID 7967 | — |
| Reactant | cis-2-BUTENE | HCID 5287573 | — |
| Solvent | Benzene | HCID 241 | — |
| Product | 7,12-Dioxaspiro(5,6)dodec-9-ene | HCID 260941 | — |
Reaction Steps
Cis-but-2-ene, 4-diol (50 g), cyclohexanone (50 g) and SNCA catalyst (2.5 g) were refluxed in benzene (75 ml) using a Deanstark water separator. The catalyst was filtered, the solvent evaporated and the residue distilled at 80°-85° C./4 torr to give 7,12-dioxaspiro[5,6]dodec-9-ene of formula III (92%) of the drawings.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US05728848 |
| Source dataset | uspto-grants-1998_03 |
| ORD ID | ord-2751c75ddf0c486a8d95a650128f9c7e |
| Source note | uspto-grants-1998_03 |