Water → HCID 178419936, compound

HRID 235276

Reaction equation

HRID 235276 reaction equation
[C:1]([C:3]1[CH:12]=[CH:11][C:10]2[C:5](=[CH:6][CH:7]=[CH:8][CH:9]=2)[CH:4]=1)#[N:2].[N-:13]=[N+:14]=[N-:15].[Na+].[Cl-].[Li+].O>COCCO>[CH:4]1[C:5]2[C:10](=[CH:9][CH:8]=[CH:7][CH:6]=2)[CH:11]=[CH:12][C:3]=1[C:1]1[NH:15][N:14]=[N:13][N:2]=1

Participants

6

Reactant 4

HCID 962WaterHCID 119442-NaphthalenecarbonitrileHCID 33557Sodium AzideHCID 433294Lithium Chloride

Product 1

HCID 178419936HCID 178419936, compound

Reagents, catalysts & solvents 1

HCID 80192-MethoxyethanolSolvent

Procedure

A mixture of 10 g of 2-cyanonaphthalene, 10.61 g of sodium azide, and 7.67 g of lithium chloride was placed in a reaction vessel, and 240 ml of 2-methoxyethanol serving as a solvent was added thereto. The above mixture was refluxed with stirring for 80 hours. The mixture was cooled to room temperature, and 500 ml of water was added to the mixture.

Workup

  1. customwas placed in a reaction vessel
  2. temperatureThe above mixture was refluxed

Sources & evidence

ORD record
ord-137d0e3b02b449b0bb19965f452b207a
Source dataset
uspto-grants-1997_01
Patent number
US05597925

Linked notes

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