L-Glutamic Acid → N-[N-[3-(9-octadecenoyloxy)-11-eicosenoyl]-L-valyl]-L-glutamic acid
Reaction equation
[C:1]([O:20][CH:21]([CH2:33][CH2:34][CH2:35][CH2:36][CH2:37][CH2:38][CH2:39][CH:40]=[CH:41][CH2:42][CH2:43][CH2:44][CH2:45][CH2:46][CH2:47][CH2:48][CH3:49])[CH2:22][C:23]([NH:25][C@H:26]([C:30](O)=[O:31])[CH:27]([CH3:29])[CH3:28])=[O:24])(=[O:19])[CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH:9]=[CH:10][CH2:11][CH2:12][CH2:13][CH2:14][CH2:15][CH2:16][CH2:17][CH3:18].[NH2:50][C@H:51]([C:57]([OH:59])=[O:58])[CH2:52][CH2:53][C:54]([OH:56])=[O:55]>>[C:1]([O:20][CH:21]([CH2:33][CH2:34][CH2:35][CH2:36][CH2:37][CH2:38][CH2:39][CH:40]=[CH:41][CH2:42][CH2:43][CH2:44][CH2:45][CH2:46][CH2:47][CH2:48][CH3:49])[CH2:22][C:23]([NH:25][C@H:26]([C:30]([NH:50][C@H:51]([C:57]([OH:59])=[O:58])[CH2:52][CH2:53][C:54]([OH:56])=[O:55])=[O:31])[CH:27]([CH3:29])[CH3:28])=[O:24])(=[O:19])[CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH:9]=[CH:10][CH2:11][CH2:12][CH2:13][CH2:14][CH2:15][CH2:16][CH2:17][CH3:18]Participants
3
Procedure
Starting from N-[3-(9-octadecenoyloxy)-11-eicosenoyl]-L-valine (2.7 g) and L-glutamic acid (2.2 g), N-[N-[3-(9-octadecenoyloxy)-11-eicosenoyl]-L-valyl]-L-glutamic acid (1.0 g) was obtained as powder according to a similar manner to that of Example 2.
Sources & evidence
- ORD record
- ord-0531239087444516ad3c28429b7494b8
- Source dataset
- uspto-grants-1987_02