2-Aminomethyl-4-tert-butyl-6-iodophenol hydrochloride → 5-tert-Butyl-2-hydroxy-3-(methylthio)benzaldehyde

HRID 236921

Reaction equation

HRID 236921 reaction equation
Cl.NCC1C=C(C(C)(C)C)C=C(I)C=1[OH:15].Cl.N[CH2:18][C:19]1[CH:24]=[C:23]([C:25]([CH3:28])([CH3:27])[CH3:26])[CH:22]=[C:21]([S:29][CH3:30])[C:20]=1[OH:31]>>[CH3:30][S:29][C:21]1[CH:22]=[C:23]([C:25]([CH3:28])([CH3:27])[CH3:26])[CH:24]=[C:19]([CH:18]=[O:15])[C:20]=1[OH:31]

Participants

3

Reactant 2

HCID 126342632-Aminomethyl-4-tert-butyl-6-iodophenol hydrochlorideHCID 213146452-Aminomethyl-4-(1,1-dimethylethyl)-6-(methylthio)phenol hydrochloride

Product 1

HCID 130974015-tert-Butyl-2-hydroxy-3-(methylthio)benzaldehyde

Procedure

This compound is prepared essentially by the same procedure as described in Example 3, Step A, except that the 2-aminomethyl-4-(1,1-dimethylethyl)-6-iodophenol hydrochloride is replaced by 2-aminomethyl-4-(1,1-dimethylethyl)-6-(methylthio)phenol hydrochloride. Thereby is obtained 3-methylthio-5-(1,1-dimethylethyl)salicylaldehyde.

Workup

  1. customThis compound is prepared essentially by the same procedure

Sources & evidence

ORD record
ord-ee3c2c4ac748432e932e27d080819bf0
Source dataset
uspto-grants-1979_06
Patent number
US04159279

Linked notes

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