Aniline → 3-Phenylammonio-1-propanesulfonate
Reaction equation
[NH2:1][C:2]1[CH:7]=[CH:6][CH:5]=[CH:4][CH:3]=1.[CH2:8]1[S:12](=[O:14])(=[O:13])[O:11][CH2:10][CH2:9]1>C(#N)C>[C:2]1([NH2+:1][CH2:10][CH2:9][CH2:8][S:12]([O-:14])(=[O:13])=[O:11])[CH:7]=[CH:6][CH:5]=[CH:4][CH:3]=1Participants
4
Reactant 2
Product 1
Reagents, catalysts & solvents 1
Procedure
A mixture of aniline (7 mmol) and propane sultone (10 mmol) was heated in 10 mL of acetonitrile at 12.0-130° C. for 9 h in a pressure tube under argon atmosphere. The product was allowed to cool to room temperature and the solid of 3-phenylammonio-1-propanesulfonate was filtered and air-dried. Yield: 95%.
Workup
- filtrationthe solid of 3-phenylammonio-1-propanesulfonate was filtered
- customair-dried
Sources & evidence
- ORD record
- ord-f03ab8001ee74a3fa69d20bb82c32bc4
- Source dataset
- uspto-grants-2014_02
- Patent number
- US08642014B2
Reaction notes
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