HuagongsheHuagongshe Chemistry Print Report · For research reference only
Sodium Acetate → Methyl dihydrojasmonate, cis-(+)-
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Sodium Acetate | HCID 517045 | — |
| Reactant | methyl (+)-(1R,2S,3R)-3-hydroxy-2-pentyl-1-cyclopentaneacetate | HCID 7075801 | — |
| Reactant | HCID 178418287 | HCID 178418287 | — |
| Product | Methyl dihydrojasmonate, cis-(+)- | HCID 1738122 | 94.9% |
Reaction Steps
This ester (2.85 g) was then oxidized by means of PCC, in the presence of sodium acetate, in a manner analogous to the method described in Example 1 d), to yield 2.68 g of the desired methyl (+)-(1R)-cis-3-oxo-2-pentyl-1-cyclopentaneacetate (colorless oil; purity 98.5%; yield 92.7%).
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US05728866 |
| Source dataset | uspto-grants-1998_03 |
| ORD ID | ord-5e5ea1bad7f34a958fa0ed6555062f7d |
| Source note | uspto-grants-1998_03 |