4-Tert-octylphenol → (s)-2-(4-(1,1,3,3-Tetramethyl-butyl)-phenoxymethyl)-oxirane

HRID 237770

Reaction equation

[CH3:1][C:2]([C:9]1[CH:14]=[CH:13][C:12]([OH:15])=[CH:11][CH:10]=1)([CH3:8])[CH2:3][C:4]([CH3:7])([CH3:6])[CH3:5].[CH2:16]1[O:18][C@H:17]1[CH2:19]Cl>>[CH3:8][C:2]([C:9]1[CH:14]=[CH:13][C:12]([O:15][CH2:19][C@@H:17]2[CH2:16][O:18]2)=[CH:11][CH:10]=1)([CH3:1])[CH2:3][C:4]([CH3:5])([CH3:6])[CH3:7]

Participants

Reactant 2

HCID 88144-Tert-octylphenol

HCID 2734062(-)-Epichlorohydrin

Product 1

HCID 7127742(s)-2-(4-(1,1,3,3-Tetramethyl-butyl)-phenoxymethyl)-oxirane

Procedure

The title compound was prepared from 4-(1,1,3,3-tetramethyl-butyl)-phenol and R-epichlorohydrin employing the procedures as set forth in Step 1 of Example 1.

Sources & evidence

ORD record: ord-d9c1e3658a78415297ef4811c9df4d1b
Source dataset: uspto-grants-2014_02
DOI: 10.6084/m9.figshare.5104873.v1
Patent number: US08642603B2

Linked notes

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