Thionyl Chloride → 4'-n-Decylbiphenyl-4-carboxylic acid chloride

HRID 2379651

Reaction equation

HRID 2379651 reaction equation
[CH2:1]([C:11]1[CH:16]=[CH:15][C:14]([C:17]2[CH:22]=[CH:21][C:20]([C:23]([OH:25])=O)=[CH:19][CH:18]=2)=[CH:13][CH:12]=1)[CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH3:10].S(Cl)([Cl:28])=O>>[CH2:1]([C:11]1[CH:16]=[CH:15][C:14]([C:17]2[CH:22]=[CH:21][C:20]([C:23]([Cl:28])=[O:25])=[CH:19][CH:18]=2)=[CH:13][CH:12]=1)[CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH3:10]

Participants

3

Reactant 2

HCID 24386Thionyl Chloride2×HCID 114050114'-n-Decyl-4-carboxybiphenyl

Product 1

HCID 540123894'-n-Decylbiphenyl-4-carboxylic acid chloride

Procedure

After 4'-n-decyl-4-carboxybiphenyl (3.10 g) was heated under reflux for 6 hours together with an excessive amount of thionyl chloride, unaltered thionyl chloride was removed by distillation to give about 3 g of 4'-n-decylbiphenyl-4-carboxylic acid chloride.

Workup

  1. customwas removed by distillation

Sources & evidence

ORD record
ord-268bbd2b02cb424aa986af4ecfbef9e9
Source dataset
uspto-grants-1994_11
Patent number
US05364561

Linked notes

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