Potassium thiocyanate → Ethyl 2,2-diethyl-6-thiocyanohexanate

Reaction equation

Br[CH2:2][CH2:3][CH2:4][CH2:5][C:6]([CH2:14][CH3:15])([CH2:12][CH3:13])[C:7]([O:9][CH2:10][CH3:11])=[O:8].[S-:16][C:17]#[N:18].[K+]>>[CH2:12]([C:6]([CH2:14][CH3:15])([CH2:5][CH2:4][CH2:3][CH2:2][S:16][C:17]#[N:18])[C:7]([O:9][CH2:10][CH3:11])=[O:8])[CH3:13]

Participants

Reactant 2

HCID 516872Potassium thiocyanate

HCID 10516776Ethyl 6-bromo-2,2-diethylhexanate

Product 1

HCID 10563119Ethyl 2,2-diethyl-6-thiocyanohexanate

Procedure

Using ethyl 6-bromo-2,2-diethylhexanate as obtained in Reference Example 10and potassium thiocyanate, the title compound was produced in the same manner as in Reference Example 11.

Sources & evidence

ORD record: ord-c37c4431b7754b35b712c746d717e26b
Source dataset: uspto-grants-1996_02
DOI: 10.6084/m9.figshare.5104873.v1
Patent number: US05491145

Reaction notes

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