3,3-Dichloro-1,1,1,2,2-pentafluoropropane → 3,3-Dichloro-1,1,1,2,2-pentafluoropropane

HRID 239852

Reaction equation

HRID 239852 reaction equation
ClCC(F)C(F)(F)F.[Cl:9][CH:10]([Cl:18])[C:11]([F:17])([F:16])[C:12]([F:15])([F:14])[F:13]>>[Cl:9][C:10]([Cl:18])=[C:11]([F:16])[C:12]([F:15])([F:14])[F:13].[Cl:9][CH:10]([Cl:18])[C:11]([F:17])([F:16])[C:12]([F:15])([F:14])[F:13]

Participants

4

Reactant 2

HCID 611123,3-Dichloro-1,1,1,2,2-pentafluoropropane2×HCID 536376231-Chloro-2,3,3,3-tetrafluoropropane

Product 2

HCID 611123,3-Dichloro-1,1,1,2,2-pentafluoropropaneHCID 109869361,1-Dichloro-2,3,3,3-tetrafluoroprop-1-ene

Procedure

The process for producing tetrafluoropropenes of the present invention comprises contacting a raw material composition comprising 1-chloro-2,3,3,3-tetrafluoropropane (HCFC-244eb) and dichloropentafluoropropane including 1,1-dichloro-2,2,3,3,3-pentafluoropropane (HCFC-225ca) and at least one of its isomers, with an alkali aqueous solution in the presence of a phase-transfer catalyst, to produce 1,1-dichloro-2,3,3,3-tetrafluoropropene (CFO-1214ya) from the 1,1-dichloro-2,2,3,3,3-pentafluoropropane (HCFC-225ca), and to produce 2,3,3,3-tetrafluoropropene 1234yf) from the 1-chloro-2,3,3,3-tetrafluoropropane (HCFC-244eb).

Sources & evidence

ORD record
ord-056549b4c4f8448d94ab3ddb5c4ded55
Source dataset
uspto-grants-2014_02
Patent number
US08642820B2

Linked notes

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