2-Diazonio-3-oxoprop-1-en-1-olate → HCID 86628158, compound
Reaction equation
[N+:1](=[C:3](C=O)[CH:4]=O)=[N-:2].[Cl-].[CH3:9][O:10][C:11]1[CH:12]=[C:13]([CH:15]=[CH:16][C:17]=1[O:18][CH3:19])[NH2:14]>>[CH3:9][O:10][C:11]1[CH:12]=[C:13]([N:14]2[CH:4]=[CH:3][N:1]=[N:2]2)[CH:15]=[CH:16][C:17]=1[O:18][CH3:19]Participants
3
Procedure
The derivative (114m) was prepared with 80.0% of output, as of the reaction of diazomalonaldehyde with the 3,4-dimethoxyaniline chloride, thus obtaining an amorphous yellow solid with fusion point at 170.0-171.0° C.
Workup
- customthus obtaining an amorphous yellow solid with fusion point at 170.0-171.0° C.
Sources & evidence
- ORD record
- ord-38545452e19447aba639f85444ae7f8b
- Source dataset
- uspto-grants-2014_08
- Patent number
- US08796316B2
Reaction notes
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