Neodymium citrate → Neodymium sesquicarbonate

HRID 2405535Notes

Reaction equation

[C:1](=[O:4])([OH:3])[O-:2].[Mg+2].[C:6](=[O:9])([OH:8])[O-:7].C([O-])(=O)CC(CC([O-])=O)(C([O-])=O)O.[Nd+3:23]>>[C:1](=[O:2])([O-:4])[O-:3].[Nd+3:23].[C:6](=[O:7])([O-:9])[O-:8].[C:1](=[O:2])([O-:4])[O-:3].[Nd+3:23]

Participants

Reactant 2

HCID 76356Neodymium citrate

HCID 102204Magnesium bicarbonate

Product 1

HCID 167103Neodymium sesquicarbonate

Procedure

Adding 6.7 m3 of the above magnesium bicarbonate solution into a reactor containing 6 m3 of neodymium citrate solution (0.27 mol/L) to react for half an hour at 35° C., and controlling the pH value of mother liquor at 5.7, RE ions are precipitated. And then neodymium carbonate is obtained after 12-hours-aging, filtration, washing and drying.

Workup

customto react for half an hour at 35° C.
customare precipitated

Sources & evidence

ORD record: ord-57224df8f073421187fced865c956d68
Source dataset: uspto-grants-2014_08
DOI: 10.6084/m9.figshare.5104873.v1
Patent number: US08808660B2

Reaction notes

Loading…