HuagongsheHuagongshe Chemistry Print Report · For research reference only
HRID 240764Generated: October 27, 2026
Benzyl azide → 1-Benzyl-5-methyl-4-(tributylstannyl)-1H-1,2,3-triazole
https://huagongshe.com/reaction/240764
Participants
| Role | Name | HCID | Charge |
|---|
| Reactant | Benzyl azide | HCID 12152 | — |
| Reactant | Tributyl(prop-1-yn-1-yl)stannane | HCID 2733165 | — |
| Product | 1-Benzyl-5-methyl-4-(tributylstannyl)-1H-1,2,3-triazole | HCID 68990342 | — |
Reaction Steps
Tributyl(1-propynyl)tin (3.87 g, 11.8 mmol) and benzyl azide (2.2 mL, 17.6 mmol) were combined and heated to 150° C. overnight. The mixture was purified by silica gel chromatography eluting with a gradient of 5-40% ethyl acetate in hexanes to afford the title compound. MS (ESI+) m/z 464.2 (M+H)+.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
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| Patent number | US08648069B2 |
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| Source dataset | uspto-grants-2014_02 |
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| ORD ID | ord-b4ca326d8b7d43b6a5b90edc7a946609 |
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| Source note | uspto-grants-2014_02 |
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