Iron(2+) tetrafluoroborate--water (1/2/6) → Borate(1-), tetrafluoro-, iron(2+) (2:1)
Reaction equation
O.O.O.O.O.O.[F:7][B-:8]([F:11])([F:10])[F:9].[F:12][B-:13]([F:16])([F:15])[F:14].[Fe+2:17]>ClCCl>[F:7][B-:8]([F:11])([F:10])[F:9].[F:12][B-:13]([F:16])([F:15])[F:14].[Fe+2:17]Participants
3
Reactant 1
Product 1
Reagents, catalysts & solvents 1
Procedure
To a suspension of iron(II) bis(tetrafluoroborate)hexahydrate (4.9 mg; 15 μmol) in dichloromethane was added a solution of h17 (5.0 mg; 14 μmol) in a few milliliters of dichloromethane. The solution turned from light yellow to dark orange with time within 18 hours. The solution was used as is in further polymerization study.
Workup
- customwithin 18 hours
Sources & evidence
- ORD record
- ord-f952c70f2fbe46af861191f886200573
- Source dataset
- uspto-grants-2004_11
- Patent number
- US06825356B2
Reaction notes
Loading…