4-Methylbenzenethiol → HCID 19764849, compound

HRID 248094

Reaction equation

[C:1]1([CH3:8])[CH:6]=[CH:5][C:4]([SH:7])=[CH:3][CH:2]=1.[Br:9][C:10]1[CH:15]=[C:14]([C:16]([F:19])([F:18])[F:17])[CH:13]=[C:12](F)[CH:11]=1>>[C:1]1([CH3:8])[CH:6]=[CH:5][C:4]([S:7][C:12]2[CH:13]=[C:14]([C:16]([F:18])([F:17])[F:19])[CH:15]=[C:10]([Br:9])[CH:11]=2)=[CH:3][CH:2]=1

Participants

Reactant 2

HCID 78114-Methylbenzenethiol

HCID 27363233-Bromo-5-fluorobenzotrifluoride

Product 1

HCID 19764849HCID 19764849, compoundYield 63%

Procedure

Using a similar procedure to that described in the 1st paragraph of Note a. above 4-toluenethiol was reacted with 1-bromo-3-fluoro-5-trifluoromethylbenzene to give 3-bromo-5-trifluoromethylphenyl 4-tolyl sulphide in 63% yield as an oil.

Sources & evidence

ORD record: ord-bdb4bed397164cd9a7fef44ca74741dc
Source dataset: uspto-grants-1993_05
DOI: 10.6084/m9.figshare.5104873.v1
Patent number: US05208259

Linked notes

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